Yes there are richest Pakistani men and richest Families families. Probabily not in words 100 richest.
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1 - Mian Muhammad Mansha Yaha Pakistan
Ranking: 1, Worth: £1.25b ($2.5billion), Industry: Businessman
2 - Asif Ali Zardari Pakistan (Mr 10%, corrupt one, unfortunatly president of Pakistan)
Ranking: 2, Worth: £900m ($1.8billion), Industry: Politics+ stolen Money all of it
3 - Sir Anwar Pervaiz UK
Ranking: 3, Worth: £750m ($1.5billion), Industry: Businessman
4 - Nawaz Sharif & Shahbaz Sharif family Saudi Arabia/Pakistan
Ranking: 4, Worth: £700m ($1.4billion), Industry: Politics/Businessman+sold pakistan to house of saud and is also known as mian chore(theif)
5 - Saddaruddin Hashwani Pakistan
Ranking: 5, Worth: £550m ($1.1billion), Industry: Businessman
6 - Nasir Schon & family U.A.E/Pakistan
Ranking: 6, (tied at 6) Worth: £500m ($1billion), Industry: Businessman
7 - Abdul Razzaq Yakoub & family U.A.E
Ranking: 6 (tied at 6), Worth: £500m ($1billion), Industry: Businessman
8 - Rafiq Habib & Rasheed Habib Pakistan
Ranking: 7, Worth: £450m ($900), Industry: Businessman
9 - Tariq Saigol & Nasim Saigol Pakistan
Ranking: 8, Worth: £425m ($850), Industry: Businessman
10 - Dewan Yousaf Farooqui Pakistan
Ranking: 9 (tied at 9), Worth: £400m ($800), Industry: Businessman
There are more you can check from here