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Future Supply of Tritium Explosive Puts US Nuclear Arsenal in Doubt

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Future Supply of Tritium Explosive Puts US Nuclear Arsenal in Doubt

The Tritium Deficit
By ROBERT ALVAREZ

In a recent report to the U.S. House Armed Services Committee, the Government Accountability Office concluded that the National Nuclear Security Agency (NNSA) in the Energy department is [B][COLOR="Blue"]“unable to overcome technical challenges” [/COLOR][/B] to producing tritium (H3) in a commercial power reactor for the U.S. nuclear arsenal. As a result the ability to provide new supplies of this radioactive isotope used to enhance the explosive power of nuclear weapons “is in doubt.”

Tritium is a radioactive isotope of hydrogen and is an important part of any modern nuclear arsenal. It is why thermonuclear weapons are known as “H-bombs.” Tritium is used in modern nuclear weapons to boost the explosive power of plutonium, which in turn, creates enough heat to cause hydrogen atoms to fuse together. This releases a tremendous amount of destructive energy, in the same process that fuels the sun and stars.

Because of its half-life of 12.3 years, tritium has to be periodically replenished in weapons. From 1954 to 1988, tritium was produced in government reactors, which were closed for safety reasons. In 1993, GAO concluded that tritium supplies from nuclear arms reductions were adequate to meet warhead needs until 2012. After that year, GAO concluded that a new tritium production capability would be needed.

In response, the Department of Energy decided in the late 1990’s to produce new supplies in a commercial power reactor, using new tritium-producing burnable absorber rods (TBARs). They contain lithium-aluminate pellets lined with zirconium, and are clad into long pencil-shaped, stainless steel rods. Tritium is produced when the atoms of lithium-6 absorbs neutrons in the reactor core.

However, the rods cannot fully contain the tritium, which is permeating into the reactor cooling system, approaching safety limits set by the Nuclear Regulatory Commission (NRC). To meet projected tritium requirements, additional TVA reactors may be required. NNSA has not yet coordinated this with the NRC, which must approve any such reactor changes.

A reserve stockpile of tritium has yet to be tapped and its size remains classified. Nor is it clear how much more tritium is expected to come from the pending START II arms reduction agreement with Russia, now before the U.S. Senate. Nonetheless, GAO remains concerned. “If NNSA takes longer than expected to increase tritium production, even reserve quantities may be insufficient to meet requirements for an extended period of time.”

Tritium production alternatives include building a new government production reactor or the development of linear accelerators. Both are likely cost billions of dollars and take several years to bring on line.

However, expanding the production of tritium for nuclear weapons in commercial nuclear power plants further undermines the long-standing barrier between military and civilian nuclear energy applications – a key element of U.S. nuclear non-proliferation policy.

This is a situation where public debate and greater transparency by the U.S. nuclear weapons program is sorely needed.

Robert Alvarez, an Institute for Policy Studies senior scholar, served as senior policy adviser to the Energy Department's secretary from 1993 to 1999.
 
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Thats why the US had initiated a nuclear deal with nuclear outcast India, who has the world´s best technology to extract tritium - without which US means nothing.
 
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Tritium Production


Tritium ( 3 H) is essential to the construction of boosted-fission nuclear weapons. A boosted weapon contains a mixture of deuterium and tritium, the gases being heated and compressed by the detonation of a plutonium or uranium device. The D-T mixture is heated to a temperature and pressure such that thermonuclear fusion occurs. This process releases a flood of 14 MeV neutrons which cause additional fissions in the device, greatly increasing its efficiency.

The tritium beta decay to 3 He (mean beta particle energy 5.7 keV; decay energy 18.6 keV) can be easily detected or can cause some other compound to fluoresce. Tritium is therefore used as a radioactive tracer element in biological research in the form of tritiated water (HTO or T 2 O) and also used in capsules surrounded by a fluo-rescing compound (e.g., zinc sulfide) to provide illumination which must be independent of the electricity supply. For example, it is used in emergency exit signs, self-luminous airport runway and helicopter pad lights, and light wands for use in directing traffic.

The low energy of the beta decay means that tritium is not an external radiation hazard because the charged decay products are stopped by 0.2 mil of water or a similar shield. However, tritium can pose an internal radiation hazard if tritiated water vapor is inhaled or absorbed through the skin. Because of its higher mass and consequent lower chemical activity, tritium gas is less strongly absorbed by the body, whether through the lungs or the skin.

Nuclear physics experiments in which tritium is compared to 3He have been important to our understanding of fundamental properties of the nuclear force.

Tritium is rare in nature because of its 12.4-year half-life. It is produced by cosmic radiation in the upper atmosphere where it combines with oxygen to form water. It then falls to earth as rain, but the concentration is too low to be useful in a nuclear weapons program. Most tritium is produced by bombarding 6Li [ 6 Li(n, a) 3 H] with neutrons in a reactor; it is also produced as a byproduct of the operation of a heavy-water-moderated reactor when neutrons are captured on the deuterons present. It has been suggested that it may be feasible to produce tritium in an accelerator (electronuclear breeder) in which protons bombard an appropriate target.

Tritium can be stored and shipped as a gas, a metal hydride (e.g., of titanium) or tritide, and trapped in zeolites (hydrated aluminum silicate compounds with uniform size pores in their crystalline structure). Stainless-steel cylinders with capacities up to 5.6 ´ 10 7 GBq (1.5 MCi) of tritium gas are used for transportation and storage and must be constructed to withstand the additional pressure which will build up as tritium gradually decays to 3 He.

All five declared nuclear weapon states must have the underlying capability to manufacture and handle tritium, although the United States has shut down its production reactors due to safety considerations. Canada manufactures tritium as a byproduct of the operation of CANDU reactors. In principle, limited amounts of tritium could be made in any research reactor with the ability to accept a target to be irradiated.

References
Adapted from - Nuclear Weapons Technology Militarily Critical Technologies List (MCTL) Part II: Weapons of Mass Destruction Technologies
 
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