China won't stay where it is now. Chinese companies are also researching and developing all alternatives. China also leads in Na battery and solid state battery.
Unbeknownst to some members here, China has been researching many other types of batteries(like the ones you mentioned above), including Zinc Ion for awhile now. Challenges still must be overcomed before mass production. LOL China is far from being "cut out".
_________________________________________________________________________
Aqueous zinc-ion battery with cycling stability of over 3,000 cycles
Conceived by scientists in China, the battery was built with a special hydrogel electrolyte made of polyacrylamide (PAM), zinc sulfate (ZnSO4), glycerol (GL), and acetonitrile (AN). The device showed high cycling stability of over 3,000 cycles, a high reversibility thanks to a Coulombic efficiency of up to 99.5%, and electrochemical performance of 185 mAh·g over 10,000 cycles.
FEBRUARY 21, 2022
EMILIANO BELLINI
The stability of hydrogel electrolyte and battery device.
Image: Chinese Academy of Sciences
Zinc-ion batteries have the potential for good energy storage performance out of cheap, abundant materials. Their performance and stability, however, remain a major hurdle to overcome in order to bring them closer to a wider commercial maturity. This storage technology, on the other hand, offers the advantage that, at the industrial level, it could potentially use many of the manufacturing processes already developed for lithium-ion batteries, making them far easier than other materials to scale up.
With this in mind, scientists from the
Chinese Academy of Sciences have developed an aqueous
zinc-ion battery based on a special hydrogel electrolyte that is claimed to offer more stability and larger capacity.
The electrolyte was made with polyacrylamide (PAM), zinc sulfate (ZnSO4), glycerol (GL), and acetonitrile (AN). These compounds are said to offer remarkable mechanical properties, high ionic conductivity, and modulated bonding interaction. Furthermore, the researchers added acrylamide (AM) and N,N ‘-methylene bisacrylamide (MBA) into the mixture to address the typical issue of zinc-ion batteries — the poor stability and performance in the wide temperature range of -20 to 60 degrees Celsius.
“The copolymer of acrylamide and N,N ‘-methylene diacrylamide is the 3D framework of hydrogel electrolyte, and zinc salt is the zinc source,” they explained. “The copolymer increased the proportion of intermolecular hydrogen bond between copolymer and water molecule, but decreased the proportion of intramolecular hydrogen bond between water molecule. The bonding interaction regulation can reduce the chance of freezing at low temperature and evaporation at high temperature, which is beneficial to expand the operating temperature range.”
The battery showed high cycling stability of over 3,000 cycles, a high reversibility thanks to a Coulombic efficiency of up to 99.5%, and electrochemical performance of 185 mAh·g over 10,000 cycles. “Another advantage of this hydrogel electrolyte is its good mechanical properties for flexible device applications,” the research team emphasized. “The voltage of the zinc-ion battery device remained constant after it was bent at different angles.”
The battery was presented in the paper
Bonding interaction regulation in hydrogel electrolyte enable dendrite-free aqueous zinc-ion batteries from −20 to 60 °C, published in the
Chemical Engineering Journal.
Conceived by scientists in China, the battery was built with a special hydrogel electrolyte made of polyacrylamide (PAM), zinc sulfate (ZnSO4), glycerol (GL), and acetonitrile (AN). The device showed high cycling stability of over 3,000 cycles, a high reversibility thanks to a Coulombic...
www.pv-magazine.com